A first-time fusion of TiNbWMoZrOx high entropy oxide (HEO) with zinc-tellurite glass: Toward superior physical properties

dc.authorscopusidHüseyin Ozan Tekin / 56971130700
dc.authorwosidHüseyin Ozan Tekin / J-9611-2016
dc.contributor.authorKılıç, Gökhan
dc.contributor.authorGüler, Ömer
dc.contributor.authorKavaz, Esra
dc.contributor.authorİlik, Erkan
dc.contributor.authorGüler, Seval Hale
dc.contributor.authorALMisned, Ghada
dc.contributor.authorTekin, Hüseyin Ozan
dc.date.accessioned2025-04-18T08:26:34Z
dc.date.available2025-04-18T08:26:34Z
dc.date.issued2024
dc.departmentİstinye Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Bilgisayar Mühendisliği Bölümü
dc.description.abstractWhile numerous oxide additives have traditionally been employed to enhance the radiation shielding capabilities of glasses, the unique attributes of high-entropy oxides (HEOs), a group of materials acclaimed in contemporary material science for their distinctive properties have remained unexamined in this specific area. This novel study explores the enhancement of radiation shielding properties in zinc-tellurite glasses through the integration of TiNbWMoZrOx High Entropy Oxides (HEO). Utilizing advanced synthesis techniques, including mechanical alloying and oxidation, the research successfully incorporates HEOs into glass matrices, aiming to improve gamma-ray and neutron attenuation. Characterization through X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) confirms the uniform distribution and structural integrity of the HEOs within the glasses. The synthesis of glass samples with a base structure suitable for the molar composition of 25ZnO.75TeO2 (mol%) and glass samples doped with TiNbWMoZrOx (HEO) was carried out using the traditional high-temperature melting and annealing method. The outcomes demonstrate a concentration-dependent increase in shielding efficacy, particularly highlighting the superior performance of glasses doped with 4 mol% of TiNbWMoZrOx (HEC2–4), which exhibit significantly enhanced mass attenuation coefficients, lower half-value layers, and higher effective atomic numbers. This indicates the effective role of HEOs in boosting radiation protection capabilities. Comparative analysis with traditional shielding materials showcases the HEC2–4 glasses' competitive advantage, underlining their potential as a versatile shielding solution. It can be concluded that incorporating TiNbWMoZrOx high entropy oxides into zinc-tellurite glasses significantly augments their radiation shielding properties, offering a novel approach for enhancing protection against gamma-ray and neutron in various applications. © 2024 Elsevier B.V.
dc.description.sponsorshipPrincess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R149), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.The authors would like to express their deepest gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R149), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
dc.identifier.citationKilic, G. Ö. K. H. A. N., Güler, Ö., Kavaz, E., Ilik, E. R. K. A. N., Guler, S. H., ALMisned, G., & Tekin, H. O. (2024). A first-time fusion of TiNbWMoZrOx high entropy oxide (HEO) with zinc-tellurite glass: Toward superior physical properties. Journal of Non-Crystalline Solids, 642, 123161.
dc.identifier.doi10.1016/j.jnoncrysol.2024.123161
dc.identifier.issn00223093
dc.identifier.scopus2-s2.0-85200575491
dc.identifier.scopusqualityQ1
dc.identifier.urihttp://dx.doi.org/10.1016/j.jnoncrysol.2024.123161
dc.identifier.urihttps://hdl.handle.net/20.500.12713/6562
dc.identifier.volume642
dc.identifier.wosWOS:001292558800001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakScopus
dc.indekslendigikaynakWeb of Science
dc.institutionauthorTekin, Hüseyin Ozan
dc.institutionauthoridHüseyin Ozan Tekin / 0000-0002-0997-3488
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Non-Crystalline Solids
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAdditives
dc.subjectAtoms
dc.subjectCompetition
dc.subjectEntropy
dc.subjectGlass
dc.subjectMechanical Alloying
dc.subjectNeutrons
dc.subjectScanning Electron Microscopy Tellurium Compounds
dc.subjectX ray Photoelectron Spectroscopy
dc.subjectZinc Compounds
dc.titleA first-time fusion of TiNbWMoZrOx high entropy oxide (HEO) with zinc-tellurite glass: Toward superior physical properties
dc.typeArticle

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