Development of dispersive solid phase extraction method for the preconcentration of parathion ethyl as a simulant of nerve agent sarin from soil, plant and water samples prior to GC–MS determination

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dc.authorscopusidSüleyman Bodur / 57202493954
dc.authorwosidSüleyman Bodur / AHB-4581-2022
dc.contributor.authorBodur, Süleyman
dc.contributor.authorBodur, Sezin Erarpat
dc.contributor.authorTutar, Bahar Karademir
dc.contributor.authorBakırdere, Sezgin
dc.contributor.authorYağmuroğlu, Ozan
dc.date.accessioned2025-04-18T09:02:20Z
dc.date.available2025-04-18T09:02:20Z
dc.date.issued2024
dc.departmentİstinye Üniversitesi, Eczacılık Fakültesi, Eczacılık Temel Bilimleri Bölümü
dc.description.abstractIn the presented study, an efficient and fast analytical method was developed for the determination of parathion ethyl as sarin simulant by gas chromatography–mass spectrometry (GC–MS). Dispersive solid phase extraction (DSPE) was performed to concentrate parathion ethyl from soil, plant and water samples. Reduced graphene oxide–iron (II, III) oxide (rGO-Fe3O4) nanocomposite was used as an adsorbent to collect the target analyte from the aqueous sample solutions. After the optimization of extraction/preconcentration parameters, optimum conditions for adsorbent amount, eluent type, mixing type/period, eluent volume and initial sample volume were determined as 15 mg, acetonitrile, vortex/30 s, 100 µL and 10 mL, respectively. Under the optimum conditions, analytical performance of the developed DSPE-GC–MS method was evaluated in terms of limit of detection (LOD), limit of quantitation (LOQ) and dynamic range. Dynamic range, LOD and LOQ values were figured out to be 0.94–235.15 µg/kg, 0.41 µg/kg and 1.36 µg/kg (mass based), respectively. Satisfactory percent recovery results (90.3–125% for soil, 93.5–108.7% for plant, 88.5–112.9% for tap water) were achieved for soil, plant and tap water samples which proved the accuracy and applicability of the developed method. It is predicted that the DSPE-GC–MS method can be accurately used for the detection of sarin in soil, plant and water samples taken from war territories. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024.
dc.identifier.citationBodur, S., Bodur, S. E., Tutar, B. K., Bakırdere, S., & Yağmuroğlu, O. (2024). Development of dispersive solid phase extraction method for the preconcentration of parathion ethyl as a simulant of nerve agent sarin from soil, plant and water samples prior to GC–MS determination. Environmental Monitoring and Assessment, 196(9), 829.
dc.identifier.doi10.1007/s10661-024-13007-0
dc.identifier.issn01676369
dc.identifier.issue9
dc.identifier.pmid39167268
dc.identifier.scopus2-s2.0-85201659818
dc.identifier.scopusqualityQ2
dc.identifier.urihttp://dx.doi.org/10.1007/s10661-024-13007-0
dc.identifier.urihttps://hdl.handle.net/20.500.12713/6670
dc.identifier.volume196
dc.identifier.wosWOS:001295904100001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.indekslendigikaynakWeb of Science
dc.institutionauthorBodur , Süleyman
dc.institutionauthoridSüleyman Bodur / 0000-0002-2994-9047
dc.language.isoen
dc.publisherSpringer Science and Business Media Deutschland GmbH
dc.relation.ispartofEnvironmental Monitoring and Assessment
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemical Weapon
dc.subjectDispersive Solid Phase Extraction
dc.subjectParathion Ethyl
dc.subjectSarin Gas
dc.titleDevelopment of dispersive solid phase extraction method for the preconcentration of parathion ethyl as a simulant of nerve agent sarin from soil, plant and water samples prior to GC–MS determination
dc.typeArticle

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