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Öğe A first-time fusion of TiNbWMoZrOx high entropy oxide (HEO) with zinc-tellurite glass: Toward superior physical properties(Elsevier B.V., 2024) Kılıç, Gökhan; Güler, Ömer; Kavaz, Esra; İlik, Erkan; Güler, Seval Hale; ALMisned, Ghada; Tekin, Hüseyin OzanWhile numerous oxide additives have traditionally been employed to enhance the radiation shielding capabilities of glasses, the unique attributes of high-entropy oxides (HEOs), a group of materials acclaimed in contemporary material science for their distinctive properties have remained unexamined in this specific area. This novel study explores the enhancement of radiation shielding properties in zinc-tellurite glasses through the integration of TiNbWMoZrOx High Entropy Oxides (HEO). Utilizing advanced synthesis techniques, including mechanical alloying and oxidation, the research successfully incorporates HEOs into glass matrices, aiming to improve gamma-ray and neutron attenuation. Characterization through X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) confirms the uniform distribution and structural integrity of the HEOs within the glasses. The synthesis of glass samples with a base structure suitable for the molar composition of 25ZnO.75TeO2 (mol%) and glass samples doped with TiNbWMoZrOx (HEO) was carried out using the traditional high-temperature melting and annealing method. The outcomes demonstrate a concentration-dependent increase in shielding efficacy, particularly highlighting the superior performance of glasses doped with 4 mol% of TiNbWMoZrOx (HEC2–4), which exhibit significantly enhanced mass attenuation coefficients, lower half-value layers, and higher effective atomic numbers. This indicates the effective role of HEOs in boosting radiation protection capabilities. Comparative analysis with traditional shielding materials showcases the HEC2–4 glasses' competitive advantage, underlining their potential as a versatile shielding solution. It can be concluded that incorporating TiNbWMoZrOx high entropy oxides into zinc-tellurite glasses significantly augments their radiation shielding properties, offering a novel approach for enhancing protection against gamma-ray and neutron in various applications. © 2024 Elsevier B.V.Öğe Boron nitride nanosheet-reinforced WNiCoFeCr high-entropy alloys: the role of B4C on the structural, physical, mechanical, and radiological shielding properties(Springer Science and Business Media Deutschland GmbH, 2022) Kavaz, Esra; Gül, Ali Oktay; Başgöz, Öyküm; Güler, Ömer; Almisned, Ghada; Bahçeci, Ersin; Güler, Seval Hale; Tekin, Hüseyin OzanThe synthesis and extensive characterization of newly developed boron nitride nanosheet (BNNSs)-reinforced WNiCoFeCr high-entropy alloys (HEAs) are presented. The influence of B4C on the structural, physical, mechanical, and nuclear shielding characteristics of synthesized HEAs has been widely examined in terms of its monotonic effects on the behavior changes. The internal morphology and structural characteristics of the fabricated composites are first investigated using X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy. Wear testing is used to determine the coefficient of friction as a function of sliding distance. Experimental gamma ray and neutron setups are created to determine their shielding characteristics against nuclear radiation. Finally, the shielding characteristics of nuclear radiation for gamma ray and fast neutrons are compared extensively to those of many existing and new-generation shielding materials. Among the examined samples, the S2 sample with B4C and BNNSs reinforcement had the greatest mechanical characteristics. Our findings imply that increasing B4C directly contributes to the shielding qualities of nuclear radiation. The B4C created in the structure of BNNSs contributes to the overall properties of HEAs, which are crucial for nuclear applications, since HEAs are being examined as a component of future nuclear reactors. Additionally, B4C is a very versatile material that may be used in circumstances where mechanical and nuclear shielding properties need to be enhanced for a variety of radiation energies. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.Öğe Boron nitride nanosheet-reinforced WNiCoFeCr high-entropy alloys: the role of B4C on the structural, physical, mechanical, and radiological shielding properties (vol 128, 694, 2022)(SPRINGER HEIDELBERG, 2022) Kavaz, Esra; Gül, Ali Oktay; Başgöz, Öyküm; Güler, Ömer; Almisned, Ghada; Bahçeci, Ersin; Güler, Seval Hale; Tekin, Hüseyin OzanNo Abstract Available.Öğe First-ever fusion of high entropy alloy (HEA) with glass: Enhancing of critical properties of zinc-tellurite glass through TiZrNbHfTaOx incorporation(Elsevier Ltd, 2024) Güler, Ömer; Kılıç, Gökhan; Kavaz, E; İlik, Erkan; Güler, Seval Hale; ALMisned, Ghada; Tekin, Hüseyin OzanMany oxide additives have historically been used to enhance the radiation shielding properties of glasses, yet the potential of high-entropy oxides (HEOs), which have gained popularity in material science for their unique properties, has not been explored in this context. This study is the first to investigate the radiation shielding capabilities of Zinc-Tellurite glass infused with High Entropy Oxide (HEO), specifically utilizing the novel attributes of a synthesized TiZrNbHfTa. In this study, the nuclear shielding properties of newly fabricated Zinc-Tellurite glasses doped with TiZrNbHfTaOx with a composition (25ZnO·75TeO2)100-x. (TiZrNbHfTaOx)x (x = 0, 1, 2, 3, 4 mol%) were studied. Through the synthesis of a TiZrNbHfTa HEA and its integration into glass structure, we have developed a series of novel materials with enhanced protective properties against both gamma-ray and neutron radiation. Experimental results demonstrate that the HEO-infused glass, particularly the HEC1-4 composition, significantly surpasses traditional shielding materials in neutron attenuation, evidenced by its superior effective neutron removal cross-section. Additionally, the HEC1-4 glass demonstrates improved gamma-ray shielding capabilities, with increased mass attenuation coefficients and decreased half-value layers, indicating a higher capacity for photon interaction and absorption. It can be concluded that the incorporation of High Entropy Alloys into glass matrices not only opens a new frontier in radiation shielding materials but also provides a versatile and effective solution with considerable potential for enhancing safety measures in radiation-prone environments. © 2024 Elsevier Ltd and Techna Group S.r.l.Öğe Synergistic effect of boron nitride and graphene nanosheets on behavioural attitudes of polyester matrix: Synthesis, experimental and Monte Carlo simulation studies(Elsevier Ltd, 2022) Başgöz, Öyküm; Güler, Seval Hale; Güler, Ömer; Canbay, Canan A.; Zakaly, Hesham M.H.; Issa, Shams A.M.; Almisned, Ghada; Tekin, Hüseyin OzanWe report the synergistic effects of boron nitride and graphene nanosheets on physical, structural, and nuclear radiation attenuation properties of polyester matrix-incorporated nanocomposites. Some critical material properties are thoroughly evaluated for several types of synthesized samples. Polyester is employed to strengthen graphene and boron nitride nanolayers, and their characteristics are investigated in detail. Additionally, we report the gamma-ray and fast neutron attenuation characteristics of synthesized nanocomposites to get a better understanding of the reinforcing effect as a function of material type and weight percentage. Thermal analysis findings indicate that adding graphene lowers the decomposition temperature but co-adding graphene and BNNS enhances thermal decomposition in comparison to graphene itself. Tensile tests showed that the inclusion of both GRP and GRP/BNNS strengthens the material. Among the polyester composite samples analyzed, the G3 sample with the most GNP reinforcement had the lowest HVL values throughout the broadest range of energy levels investigated. The recent findings may be beneficial to the scientific community in terms of incorporating these reinforcing types and ratios into polyester materials for a variety of applications, including industrial and research purposes. © 2022
