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Öğe Assessing geochemical and natural radioactivity impacts of Hamadat phosphatic mine through radiological indices(Public Library Science, 2023) Fathy, Douaa; Zakaly, Hesham M. H. S.; Lasheen, El Saeed R.; Elsaman, Reda A.; Alarifi, Saad; Sami, Mabrouk; Awad, HamdyThe utilization of phosphorite deposits as an industrial resource is of paramount importance, and its sustainability largely depends on ensuring safe and responsible practices. This study aims to evaluate the suitability of phosphorite deposits for industrial applications such as the production of phosphoric acid and phosphatic fertilizers. To achieve this goal, the study meticulously examines the geochemical characteristics of the deposits, investigates the distribution of natural Radioactivity within them, and assesses the potential radiological risk associated with their use. The phosphorites are massive and collected from different beds within the Duwi Formation at the Hamadat mining area. They are grain-supported and composed of phosphatic pellets, bioclasts (bones), non-phosphatic minerals, and cement. Geochemically, phosphorites contain high concentrations of P2O5 (23.59-28.36 wt.%) and CaO (40.85-44.35 wt.%), with low amounts of Al2O3 (0.23-0.51 wt.%), TiO2 (0.01-0.03 wt.%), Fe2O3 (1.14-2.28 wt.%), Na2O (0.37-1.19 wt.%), K2O (0.03-0.12 wt.%), and MnO (0.08-0.18 wt.%), suggesting the low contribution of the detrital material during their deposition. Moreover, they belong to contain enhanced U concentration (55-128 ppm). They are also enriched with Sr, Ba, Cr, V, and Zn and depleted in Th, Zr, and Rb, which strongly supports the low detrital input during the formation of the Hamadat phosphorites. The high Radioactivity of the studied phosphorites is probably due to the widespread occurrence of phosphatic components (e.g., apatite) that accommodate U in high concentrations. Gamma spectrometry based on NaI (Tl) crystal 3x3 has been used to measure occurring radionuclides in the phosphorite samples. The results indicate that the radioactive concentrations' average values of Ra-226, Th-232, and K-40 are 184.18 & PLUSMN;9.19, 125.82 & PLUSMN;6.29, and 63.82 & PLUSMN;3.19 Bq Kg(,)(-1) respectively. Additionally, evaluations have been made of the radiological hazards. The calculated risk indicators exceeded the recommended national and world averages. The data obtained will serve as a reference for follow-up studies to evaluate the effectiveness of the Radioactivity of phosphatic materials collected from the Hamdat mine area.Öğe Radiometric and petrographic characterization of El-Yatima granite: Evaluating radiological risks and mineralogical features(Pergamon-elsevier science, 2024) Zakaly, Hesham M. H.; Awad, Hamdy A.; Lasheen, El Saeed R.; Issa, Shams A. M.; Elsaman, Reda; Khandaker, Mayeen Uddin; Al-awah, Hezam; Fathy, Douaa; Sami, MabroukThe current investigation aims to assess the potential of El-Yatima granitic pluton as a decorative stone by examining its natural radioactivity and mineralogical elements. Specifically, the study aims to determine the concentrations of radionuclides 40K, 232Th, and 226Ra, perform petrographic analyses, and evaluate the associated radiological risks to determine the safety and usability of the granite in construction and decoration, as well as to assess the potential of these granitic rocks as a safe and effective decorative stone for various applications. It has a 12 km2 surface area of 812 m above sea level. It is situated in the Eastern Central Desert. Its hypidiomorphic texture, medium-to-coarse grain size, and predominant composition of K-feldspars, quartz, and plagioclase are observed, along with minute amounts of muscovite and biotite. By employing NaI (Tl) gamma-ray spectroscopy, the natural radionuclide concentrations of 40K, 232Th, and 226Ra in El-Yatima granitic rocks were ascertained. Additionally, radiological concerns were identified for the materials that were examined. The average concentrations of radionuclides 40K, 232Th, and 226Ra are 178 Bqkg-1, 44 Bqkg- 1, and 41 Bqkg- 1, respectively. The following are the computed values: 117 Bqkg- 1, 0.43, 0.32, 53 nGyh-1, average radium equivalent (Raeq), hazard indices (Hin and Hex) and dose rate (D), respectively. When compared to levels typically indicated, it was discovered that its values were within the worldwide standard. The study's findings could be a starting point for radiometric data for upcoming surveillance and epidemiological research.